MoCu3TeO7Cl2·0.5H2O

Single crystals of molybdenum(VI) tricopper(II) tellurium(IV) hepta­oxide dichloride hemihydrate, MoCu₃TeO₇Cl₂·0.5H₂O, were synthesized via a transport reaction in sealed evacuated silica tubes. All atoms occupy general positions within the triclinic () unit cell. The building units are irregular CuO₄Cl and CuO₃Cl₂ square pyramids, distorted TeO₃₊₁E trigonal bipyramids (E is the lone pair of Te^IV) and irregular MoO₅ pyramids. The TeO₃₊₁E, CuO₄Cl and CuO₃Cl₂ polyhedra form (110) layers bridged by Mo atoms. The water mol­ecules are located in [100] channels.     

The representation of thermodynamic properties at high pressures

It is sometimes advantageous to have an expression for the Gibbs energy, G_m(T,P), from which one can analytically derive an expression for the Heimholtz energy, F_m(T, V_m). Such an expression is suggested for solid substances and it is shown how expressions for other physical properties can be derived from it.     

State estimation for partially observed Markov chains

Recursive equations are derived for the conditional distribution of the state of a Markov chain, given observations of a function of the state. Mainly continuous time chains are considered. The equations for the conditional distribution are given in matrix form and in differential equation form. The conditional distribution itself forms a Markov process. Special cases considered are doubly stochastic Poisson processes with a Markovian intensity, Markov chains with a random time, and Markovian approximations of semi-Markov processes. Further the results are used to compute the Radon-Nikodym derivative for two probability measures for a Markov chain, when a function of the state is observed.     

Performance Analysis with Truncated Heavy-Tailed Distributions

This paper deals with queues and insurance risk processes where a generic service time, resp. generic claim, has the form U ∧ K for some r.v. U with distribution B which is heavy-tailed, say Pareto or Weibull, and a typically large K, say much larger than . We study the compound Poisson ruin probability ψ(u) or, equivalently, the tail of the M/G/1 steady-state waiting time W. In the first part of the paper, we present numerical values of ψ(u) for different values of K by using the classical Siegmund algorithm as well as a more recent algorithm designed for heavy-tailed claims/service times, and compare the results to different approximations of ψ(u) in order to figure out the threshold between the light-tailed regime and the heavy-tailed regime. In the second part, we investigate the asymptotics as K → ∞ of the asymptotic exponential decay rate γ = γ ^(K) in a more general truncated Lévy process setting, and give a discussion of some of the implications for the approximations. AMS 2000 Subject Classification Primary 68M20, Secondary 60K25 †Partially supported by MaPhySto—A Network in Mathematical Physics and Stochastics, founded by the Danish National Research Foundation. An erratum to this article is available at .     

Alkaloids ofDelphinium grandiflorum

Chemistry of Natural Compounds -     

Bacteria counting with impedance spectroscopy in a micro probe station

A method to quantify the density of viable biological cells in suspensions is presented. The method is implemented by low-frequency impedance spectroscopy and based on the finding that immobilized ions are released to move freely in the surrounding suspension when viable Escherichia coli cells are killed by a heat shock. The presented results show that an amount of ions corresponding to approximately 2 x 10(8) unit charges are released per viable bacterium killed. A micro probe station with coplanar Ti electrodes was electrically characterized and used as a measuring unit for the impedance spectroscopy recordings. This unit is compatible with common microfabrication techniques and should enable the presented method to be employed using a flow-cell device for viable bacteria counting in miniaturized on-line monitoring systems.